内窥镜检查在电站锅炉内部检验中的应用

工业内窥镜是电站锅炉内部检验中不可或缺的设备,主要用来对集箱、减温器、受热面管等内部人眼无法观察到的地方进行检验,从而确定承压部件内部是否存在严重影响锅炉安全运行的缺陷.本文通过对锅炉内窥实例进行分析和总结,阐述内窥镜检查在锅炉内检中的重要性并给相关工作人员提供借鉴与参考.     

Effect of Soybean Cultivation on Soil Collembola Community in Marshland of Sanjiang Plain,China

The Sanjiang Plain, the largest inland freshwater marshland in China, was extensive reclaimed into agricultural land. To assess the effects of marshland reclamation on Collembola, we investigated collembolan communities in a chronosequence of soybean plantations (2, 15, and 25 years) in Sanjiang marshland, Northeastern China. We found that: 1) the densities and species richness of Collembola were promoted after short-term (2 years) cultivation of soybean, but significantly decreased after medium-term cultivation (15 years); 2) the densities of epi-edaphic Collembola increased while the densities of hemi-edaphic Collembola decreased as the elongation of soybean cultivation; 3) compared with S0, two species of Collembola appeared while five species disappeared in S25. The changes of plant communities and the soil traits were supposed to be the key factors affecting the composition of soil Collembola. We thus suggest that original marshland should be saved for preserving high diversity and densities of Collembola in the Sanjiang Plain.

     

Considering climate change and regional differences: An efficiency assessment of coal mine use and land restoration

China is the country with the largest coal mining production and consumption in the world, but due to a large amount of coal burning, air pollution and climate change are exasperating related problems. The previous literature mainly has discussed coal mine production and environmental pollution, but failed to take into account external factors such as climate change and seldom discussed the relationship between coal mine land use and land restoration. Therefore, this study uses the meta-Epsilon-Based Measure two-stage Data Envelopment Analysis under the exogenous model and incorporates coal mine land use and land restoration use into the model to explore the relationship between the two under climate change. The research results are as follows. (1) If the external climate factors are not considered, then the phenomenon of overestimation or underestimation of the technology gap arises. (2) The efficiency value of the coal mining stage in most provinces is generally higher than the land restoration efficiency value.     

Synthesis of branched allylic sulfones by regioselective boron-catalysed hydrosulfonylation

Environmental Chemistry Letters - Branched allylic sulfones are scaffolds widely distributed in bioactive molecules and organic functional materials. The synthesis of allylic sulfones has been...     

Enhanced triallyl isocyanurate (TAIC) degradation through application of an O3/UV process: Performance optimization and degradation pathways

• UV/O₃ process had higher TAIC mineralization rate than O₃ process. • Four possible degradation pathways were proposed during TAIC degradation. • pH impacted oxidation processes with pH of 9 achieving maximum efficiency. • CO₃^2– negatively impacted TAIC degradation while HCO₃^– not. • Cl^– can be radicals scavenger only at high concentration (over 500 mg/L Cl^–). Triallyl isocyanurate (TAIC, C₁₂H₁₅N₃O₃) has featured in wastewater treatment as a refractory organic compound due to the significant production capability and negative environmental impact. TAIC degradation was enhanced when an ozone(O₃)/ultraviolet(UV) process was applied compared with the application of an independent O₃ process. Although 99% of TAIC could be degraded in 5 min during both processes, the O₃/UV process had a 70%mineralization rate that was much higher than that of the independent O₃ process (9%) in 30 min. Four possible degradation pathways were proposed based on the organic compounds of intermediate products identified during TAIC degradation through the application of independent O₃ and O₃/UV processes. pH impacted both the direct and indirect oxidation processes. Acidic and alkaline conditions preferred direct and indirect reactions respectively, with a pH of 9 achieving maximum Total Organic Carbon (TOC) removal. Both CO₃^2– and HCO₃^– decreased TOC removal, however only CO₃^2– negatively impacted TAIC degradation. Effects of Cl^– as a radical scavenger became more marked only at high concentrations (over 500 mg/L Cl^–). Particulate and suspended matter could hinder the transmission of ultraviolet light and reduce the production of HO· accordingly.     

底泥性质对重金属生物淋滤效果的影响

生物淋滤技术是一项可以将重金属从污染底泥或土壤中分离出来的环境修复技术,具有反应温和、耗酸少、运行成本较低、去除效率高,以及脱毒后底泥的脱水性能好等优点。然而,底泥成分复杂、流域特异性高,这使得相似的生物淋滤工艺对不同底泥的重金属去除效果不尽相同、淋滤技术的工艺参数标准化难度增加。综述了底泥性质对淋滤反应的3方面影响:底泥中的有机质与酸可挥发性硫化物(AVS)会改变重金属的形态;pH、可还原性硫、水溶性有机物(DOM)会对淋滤功能菌的活性产生影响;底泥粒度和耗酸能力(ACC)也会影响重金属的化学淋出效果。在此基础上提出今后该技术有待开展的研究内容,以期为该技术的进一步推广应用提供理论依据和技术支撑。     

地铁多线换乘车站火灾模型实验研究—(1)模型装置设计

为研究地铁网络化运营枢纽车站火灾烟气扩散特征和防排烟技术，根据工程资料和标准规范对典型多线换乘车站进行1∶10火灾实验模型设计，并依据设计方案完成车站模型主体结构和通风排烟系统的搭建，同时在各个防烟分区设计安装温度、流速、烟气浓度和热辐射测量装置，可实现对“T”形、“十”形和“L”形换乘等不同换乘形式车站的火灾场景模拟和危险参数测量。研究结果表明:该模型装置能够开展一系列针对不同换乘形式和通风模式的火灾实验，对于全面揭示大型换乘车站火灾烟气运动规律、验证并优化火灾防排烟设计方法、支撑复杂结构枢纽车站火灾烟气控制技术具有重要意义。     

TRMM和GPM卫星降水数据在中国三大流域的降尺度对比研究

以中国三大流域为研究区域,分别针对TRMM 3B43和GPM IMERG降水数据,构建基于归一化植被指数(NDVI)和数字高程模型(DEM)数据的地理加权回归(GWR)模型,以2014年夏季(6～8月)数据为例,得到了三大流域1 km分辨率的降尺度降水数据,并进一步通过气象站点数据对降尺度结果进行验证.研究表明:(1) GPM原始数据整体精度优于TRMM数据,两种数据在黄河流域的精度评价指标优于长江流域与珠江流域;(2)经降尺度计算,两种数据空间分辨率得到了显著提高,且表现出更多降水变化的细节与趋势,但精度指标对原始数据依赖性大,导致提升并不显著;(3)当联合使用NDVI及DEM作为GWR降尺度模型的辅助变量时,两种降尺度结果的差异值在长江流域与珠江流域的高海拔地区中更为显著;(4)黄河流域中,使用不同辅助变量下的降尺度结果在空间分布上总体相似.TRMM数据使用地形作为单独辅助变量的降尺度结果最佳,而GPM数据不同辅助变量下降尺度结果差异并不明显.     

Effects of Compounded Curing Agents on Properties and Performance of Urea Formaldehyde Resin

The effects of three compounded curing agents on the properties and performance of the urea-formaldehyde (UF) resin were investigated in this study. The compounded curing agents were prepared by mixing ammonium chloride with hexamethylenetetramine, citric acid, and oxalic acid respectively at a ratio of 1:1, named N-H, N–CA, and N–OA, respectively. The curing process, crystallinity, and physical properties were measured, and the three-ply plywood was fabricated to measure its prepress strength, wet shear strength, and formaldehyde emission. Results showed that the compounded curing agents N–CA and N–OA enhanced the initial viscosity, crosslinking density and thermal stability of UF resin. Additionally, the prepress strength of the plywood bonded by UF resin with N–CA and N–OA increased by 82 and 111% respectively compared to the UF resin with NH₄Cl, and the wet shear strength increased by 14 and 16%, the formaldehyde emission decreased by 19 and 42% respectively. However, owing to the short pot-life of these curing agent limited their storage time, the curing agents N–CA and N–OA should be applied to fabricate plywood in winter for obtaining a better bond strength and a lower formaldehyde emission. While the UF resin with N–HT showed a suitable pot-life, so it could be applied to fabricate plywood in summer for long time storage and avoiding procuring problem.     

In situ electron-induced reduction of NOx via CNTs activated by DBD at low temperature

• An in situ electron-induced deNO_x process with CNT activated by DBD was achieved. • Carbon atoms on CNT surface were verified to be excited by plasma in DBD-CNT system. • Reactions between NO_x and excited C result in synergistic effect of DBD-CNT system. In this study, a new in situ electron-induced process is presented with carbon nanotubes (CNTs) as a reduction agent activated by dielectric barrier discharge (DBD) for nitrogen oxide (NO_x) abatement at low temperature (<407 K). Compared with a single DBD system and a DBD system with activated carbon (DBD-AC), a DBD system with carbon nanotubes (DBD-CNT) showed a significant promotion of NO_x removal efficiency and N₂ selectivity. Although the O₂ content was 10%, the NO_x conversion and N₂ selectivity in the DBD-CNT system still reached 64.9% and 81.9% at a specific input energy (SIE) of 1424 J/L, and these values decreased to 16.8%, 31.9% and 43.2%, 62.3% in the single DBD system and the DBD-AC system, respectively. X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM) were utilized to investigate surface changes in the CNTs after activation by DBD to explore the NO_x reduction abatement mechanism of this new process. Furthermore, the outlet gas components were also observed via Fourier transform infrared spectroscopy (FTIR) to help reveal the NO_x reduction mechanism. Experimental results verified that carbon atoms excited by DBD and the structure of CNTs contributed to the synergistic activity of the DBD-CNT system. The new deNO_x process was accomplished through in situ heterogenetic reduction reactions between the NO_x and carbon atoms activated by the plasma on the CNTs. In addition, further results indicated that the new deNO_x process exhibited acceptable SO₂ tolerance and water resistance.